From carbones to carbenes and ylides in the coordination sphere of iridium
| العنوان: | From carbones to carbenes and ylides in the coordination sphere of iridium |
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| المؤلفون: | Leon Maser, Zhuofeng Ke, Yinwu Li, Robert Langer, Lukas Alig |
| المصدر: | Dalton Transactions. 50:954-959 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Coordination sphere, Ligand, chemistry.chemical_element, Pincer movement, Catalysis, Inorganic Chemistry, chemistry.chemical_compound, Transition metal, chemistry, Ylide, Polymer chemistry, Iridium, Phosphine |
| الوصف: | The carbodiphosphorane-based iridium pincer complex (2) is demonstrated to rearrange in chlorinated organic solvents under cleavage of a P-C-bond to give a chelating phosphine ylide ligand. A detailed mechanistic investigation reveals that these types of donor groups are prone for P-C-bond cleavage in the coordination sphere of transition metal hydrido complexes. Finally, complex 2 is demonstrated to be an efficient hydrogen-borrowing catalyst. |
| تدمد: | 1477-9234 1477-9226 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::35293591cd9ac5cc5867fd2d08409d68 https://doi.org/10.1039/d0dt03942j |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....35293591cd9ac5cc5867fd2d08409d68 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14779234 14779226 |
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