Strained alkynes derived from 2,2'-dihydroxy-1,1'-biaryls; synthesis and copper-free cycloaddition with azides
| العنوان: | Strained alkynes derived from 2,2'-dihydroxy-1,1'-biaryls; synthesis and copper-free cycloaddition with azides |
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| المؤلفون: | Martin Wills, Peter B. O′ Connor, Cookson K. C. Chiu, Lavrentis-Demetrios Galanopoulos, Guy J. Clarkson, Alessandro Del Grosso |
| المصدر: | Organicbiomolecular chemistry. 15(21) |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | 010405 organic chemistry, Organic Chemistry, chemistry.chemical_element, 010402 general chemistry, 01 natural sciences, Biochemistry, Copper, Cycloaddition, 0104 chemical sciences, Catalysis, Molecular geometry, chemistry, Reagent, Polymer chemistry, Organic chemistry, QD, Physical and Theoretical Chemistry |
| الوصف: | A series of strained alkynes were prepared from 2,2′-dihydroxy-biaryls. Several were characterised by X-ray crystallography, revealing strained C(sp)–C(sp)–C(sp3) bond angles in the range of 163–167°. Their cycloadditions with azides proceed without a catalyst. Functionalised versions of these reagents have potential applications to materials synthesis and bioconjugations. |
| وصف الملف: | application/pdf |
| تدمد: | 1477-0539 1477-0520 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::35b32a25d46fc886365aebb2004ea6ee https://pubmed.ncbi.nlm.nih.gov/28513734 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....35b32a25d46fc886365aebb2004ea6ee |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14770539 14770520 |
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