Synthesis of coordination polymers based on a 2,2′-dimethoxy-1,1′-biphenyl scaffold and Hg(II), Co(II), or Zn(II)
| العنوان: | Synthesis of coordination polymers based on a 2,2′-dimethoxy-1,1′-biphenyl scaffold and Hg(II), Co(II), or Zn(II) |
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| المؤلفون: | Nathalie Kyritsakas, Pierre Mobian, El Mostafa Ketatni, Abdelaziz Jouaiti |
| المساهمون: | Polydisciplinary Faculty - Sultan Moulay Slimane University - Maroc, Université Sultan Moulay Slimane (USMS ), Chimie de la matière complexe (CMC), Université de Strasbourg (UNISTRA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| المصدر: | Journal of Molecular Structure Journal of Molecular Structure, Elsevier, 2022, 1248, pp.131466. ⟨10.1016/j.molstruc.2021.131466⟩ |
| بيانات النشر: | HAL CCSD, 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Biphenyl, chemistry.chemical_classification, Chemistry, Pyridine, Organic Chemistry, 02 engineering and technology, Crystal structure, Polymer, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 0104 chemical sciences, Analytical Chemistry, Inorganic Chemistry, Helical networks, Coordination polymers, chemistry.chemical_compound, Crystallography, [CHIM.POLY]Chemical Sciences/Polymers, 2 2'-dimethoxy-1 1'-biphenyl, [CHIM.COOR]Chemical Sciences/Coordination chemistry, 0210 nano-technology, Chirality (chemistry), Spectroscopy |
| الوصف: | International audience; In this study, 3,3'-di(pyridin-4-yl)-(2,2'-dimethoxy-[1,1'-biphenyl]) (L) was synthetized, structurally characterized by X-ray crystallography and combined with HgCl2, CoCl2, or ZnSiF6 for the formation of three coordination polymers ((HgCl2)2(L), (CoCl2)2(L)2.CHCl3, and Zn(SiF6)(L)2). The crystal structures of synthesis compound indicate the formation of different types of coordination modes, and each adopts a mono (1D) or tri-dimensional (3D) framework by C-H•••π interactions. In (CoCl2)2(L)2, the combination of Co(II) with L forms a metallomacrocycle, while in the other compounds two helical infinite networks were characterized. Compounds (HgCl2)2(L) made of two helical chains with opposite chirality (P and M), and Zn(SiF6)(L)2 exhibits helical tubular assemblies of the L attached to two Zn(SiF6) pillars. This work may pave the way to further study the chemical, structural and physicochemical properties of metal-organic coordination polymers. |
| اللغة: | English |
| تدمد: | 0022-2860 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3ab2c070b83699677f2279c30a900c48 https://hal.archives-ouvertes.fr/hal-03359084 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....3ab2c070b83699677f2279c30a900c48 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 00222860 |
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