Gradiently Polymerized Solid Electrolyte Meets with Micro-/Nanostructured Cathode Array
| العنوان: | Gradiently Polymerized Solid Electrolyte Meets with Micro-/Nanostructured Cathode Array |
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| المؤلفون: | Ji-Lie Shi, Rui Wen, Ya-Xia Yin, Taishan Wang, Chunru Wang, Xian-Xiang Zeng, Xudong Zhang, Yang Shi, Jin-Yi Li, Wei Dong, Yao Xiao, Yu-Guo Guo |
| المصدر: | ACS Applied Materials & Interfaces. 10:18005-18011 |
| بيانات النشر: | American Chemical Society (ACS), 2018. |
| سنة النشر: | 2018 |
| مصطلحات موضوعية: | Battery (electricity), Materials science, Microchannel, Nanoparticle, 02 engineering and technology, Electrolyte, Current collector, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, Cathode, 0104 chemical sciences, Anode, law.invention, Chemical engineering, law, General Materials Science, Surface layer, 0210 nano-technology |
| الوصف: | The poor contact between the solid-state electrolyte and cathode materials leads to a high interfacial resistance, severely limiting the rate capability of solid Li metal batteries. Herein, an integrative battery design is introduced with a gradiently polymerized solid electrolyte (GPSE), a microchannel current collector array, and nanosized cathode particles. An in situ formed GPSE encapsulates cathode nanoparticles in the microchannel with ductile inclusions to lower the interfacial impedance, and the stiff surface layer of GPSE toward anode suppresses the Li dendrite growth. The Li metal batteries based on GPSE and the Li-free hydrogenated V2O5 (V2O5–H) cathode exhibit an outstanding high rate response of up to 5 C (the capacity ratio of 5 C/1 C is 90.3%) and an ultralow capacity fade rate of 0.07% per cycle over 300 cycles. The other Li-containing cathodes such as LiFePO4 and LiNi0.5Mn0.3Co0.2O2 can also operate effectively at the rates of 5 and 2 C, respectively. Such an ingenious design may provide ... |
| تدمد: | 1944-8252 1944-8244 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3c222420cfd7635b80f0d96c5ae3c3a8 https://doi.org/10.1021/acsami.8b05288 |
| رقم الأكسشن: | edsair.doi.dedup.....3c222420cfd7635b80f0d96c5ae3c3a8 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 19448252 19448244 |
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