Thermodynamic and kinetic study of synthesised graphene oxide-CuO nanocomposites: a way forward to fuel additive and photocatalytic potentials

التفاصيل البيبلوغرافية
العنوان: Thermodynamic and kinetic study of synthesised graphene oxide-CuO nanocomposites: a way forward to fuel additive and photocatalytic potentials
المؤلفون: Saba Sehar, Shengfu Zhang, Ushna Khalid, Eder C. Lima, Farooq Sher, Jasmina Sulejmanović
بيانات النشر: Elsevier BV, 2020.
سنة النشر: 2020
مصطلحات موضوعية: Materials science, Oxide, 02 engineering and technology, 010402 general chemistry, 01 natural sciences, law.invention, Diesel fuel, chemistry.chemical_compound, law, Fire point, Materials Chemistry, Physical and Theoretical Chemistry, Spectroscopy, Nanocomposite, Graphene, Pour point, 021001 nanoscience & nanotechnology, Condensed Matter Physics, Atomic and Molecular Physics, and Optics, 0104 chemical sciences, Electronic, Optical and Magnetic Materials, Chemical engineering, chemistry, Flash point, Photocatalysis, 0210 nano-technology
الوصف: Rectangular shaped GO-CuO nanocomposites have gained special attention because of spectacular applications in wastewater treatment. However, due to a lack of research, the fuel additive properties of GO-CuO are still unreported. A proper synthesis and characterisation methods are necessary to investigate the fuel additive properties of GO-CuO. The present research demonstrates the synthesis of graphene oxide (GO) sheets via modified Hummers' method. Further, GO-CuO nanohybrid was prepared by fast, cost-effective, and easy to handle solvothermal approach. The crystal data such as crystal structure, unit cell parameters, space groups, crystal system, and coordinates were explained via XRD analysis. Physical and combustion properties of fuel were analysed at different concentrations (0, 20, 40, 60, and 80 ppm) of diesel-GO-CuO blend for fuel quality parameters. The flash point and fire point of pure diesel oil were observed as 78 and 80 °C which were decreased to 50 and 58 °C, respectively, at 80 ppm concentration. With GO-CuO nanocomposites, the cloud point and pour point decrease until a temperature of −8 °C and − 19 °C, respectively, with a pronounced decrease in the viscosity up to 1.83 mm2/s. Further, the photocatalytic degradation of Methylene Red (MR) dye is studied with the effect of changing H2O2, photocatalyst, and dye concentrations with time. Remarkably, the reaction kinetics and MR degradation of about 94% with sixth-time recyclability were observed. The results of this study showed improved MR degradation when using GO-CuO with H2O2. GO-CuO applications can be utilised to remove other dyes in future and to improve fuel quality parameters.
وصف الملف: application/pdf
اللغة: English
تدمد: 0167-7322
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::42922e20bd095120bc255b9e82ab4da7
https://irep.ntu.ac.uk/id/eprint/46730/1/1568057_Sher.pdf
حقوق: OPEN
رقم الأكسشن: edsair.doi.dedup.....42922e20bd095120bc255b9e82ab4da7
قاعدة البيانات: OpenAIRE