Mechanistic Aspects of Cobalt–Oxo Cubane Clusters in Oxidation Chemistry
| العنوان: | Mechanistic Aspects of Cobalt–Oxo Cubane Clusters in Oxidation Chemistry |
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| المؤلفون: | Jaruwan Amtawong, Andy I. Nguyen, T. Don Tilley |
| المصدر: | Journal of the American Chemical Society. 144:1475-1492 |
| بيانات النشر: | American Chemical Society (ACS), 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Colloid and Surface Chemistry, General Chemistry, Biochemistry, Catalysis |
| الوصف: | Cobalt oxides are recognized as one of the most efficient earth-abundant catalysts for challenging oxidation chemistry, with substrates ranging from water to organic compounds. In these oxidations, cobalt-oxo species with formal oxidation states greater than 3 are commonly invoked as reactive intermediates. However, there is a dearth of mechanistic information regarding how these high-valent cobalt catalysts operate. This Perspective describes how the study of molecular cobalt oxo clusters, with an emphasis on [Co |
| تدمد: | 1520-5126 0002-7863 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::51c14f38bc292ad41343e47a25f99788 https://doi.org/10.1021/jacs.1c11445 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....51c14f38bc292ad41343e47a25f99788 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15205126 00027863 |
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