AC conductivity, structural, and dielectric properties of zinc supported on titanium dioxide: Facile synthesis and DFT calculation

التفاصيل البيبلوغرافية
العنوان: AC conductivity, structural, and dielectric properties of zinc supported on titanium dioxide: Facile synthesis and DFT calculation
المؤلفون: M. A. H. Khalafalla, Ali H. Bashal
المصدر: Arabian Journal of Chemistry, Vol 13, Iss 10, Pp 7453-7458 (2020)
بيانات النشر: Elsevier BV, 2020.
سنة النشر: 2020
مصطلحات موضوعية: Anatase, Phase transition, Scanning electron microscope, General Chemical Engineering, Ac conductivity, Analytical chemistry, Dielectric loss, chemistry.chemical_element, 02 engineering and technology, Zinc, Dielectric, 010402 general chemistry, 01 natural sciences, lcsh:Chemistry, chemistry.chemical_compound, Phase (matter), Dielectric constant, First Principle Calculation, General Chemistry, 021001 nanoscience & nanotechnology, 0104 chemical sciences, lcsh:QD1-999, chemistry, Rutile, Titanium dioxide, Zn/TiO2, 0210 nano-technology
الوصف: We present a simple and systematic synthesis method of Zn doped TiO2 (Zn/TiO2) that is usually prepared with sophisticated preparation procedures. Zn/TiO2 have been synthesized following a facile and efficient incipient wet impregnation method. The resulting Zn/TiO2 has been characterized by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy, which revealed the successful formation of the anatase phase and traces of the rutile phase. The existence of the rutile phase in smaller proportion was a clear sign of the Zn doping induced anatase-to-rutile phase transition. Sensible enhancement in the dielectric constant due to Zn addition has also been observed from experiment and approximate first-principle calculation. Thus, our results have significant impact on TiO2 based semiconductor technology.
تدمد: 1878-5352
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6a64492f28e944c79dc62ff9e04d941b
https://doi.org/10.1016/j.arabjc.2020.08.021
حقوق: OPEN
رقم الأكسشن: edsair.doi.dedup.....6a64492f28e944c79dc62ff9e04d941b
قاعدة البيانات: OpenAIRE