Remarkable Acceleration of Benzimidazole Synthesis and Cyanosilylation Reactions in a Supramolecular Solid Catalyst
| العنوان: | Remarkable Acceleration of Benzimidazole Synthesis and Cyanosilylation Reactions in a Supramolecular Solid Catalyst |
|---|---|
| المؤلفون: | Sergio Rojas-Buzo, Avelino Corma, Pilar García-García |
| المصدر: | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia instname |
| بيانات النشر: | John Wiley & Sons, 2017. |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | Benzimidazole, Cyanosilylation, 010405 organic chemistry, Organic Chemistry, Supramolecular chemistry, Enzyme mimic, 010402 general chemistry, 01 natural sciences, Combinatorial chemistry, Catalysis, 0104 chemical sciences, Supramolecular catalyst, Inorganic Chemistry, Reaction rate, chemistry.chemical_compound, QUIMICA ORGANICA, chemistry, Organic reaction, Organic chemistry, Lewis acids and bases, Physical and Theoretical Chemistry, Metal organic catalyst |
| الوصف: | [EN] A solid metal organic catalyst with hydrophobic pockets and Lewis acid centers strongly accelerates the reaction rate for organic reactions. This is exemplified for the cyanosilylation of ketones and for the synthesis of benzimidazoles, for which very high selectivities are obtained. The solid can be recovered and reused and its behavior approaches that of a functional enzyme mimic. This work was funded by the Generalitat Valenciana (Prometeo). The Severo Ochoa program (SEV-2012-0267) is thankfully acknowledged. S. R-B acknowledges a PhD fellowship from the Generalitat Valenciana. |
| وصف الملف: | application/pdf |
| اللغة: | English |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6fcdf0655e0ecec740be2e2870574be5 https://doi.org/10.1002/cctc.201601407 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....6fcdf0655e0ecec740be2e2870574be5 |
| قاعدة البيانات: | OpenAIRE |
| الوصف غير متاح. |