Mercury Chalcogenide Nanoplatelet–Quantum Dot Heterostructures as a New Class of Continuously Tunable Bright Shortwave Infrared Emitters

التفاصيل البيبلوغرافية
العنوان: Mercury Chalcogenide Nanoplatelet–Quantum Dot Heterostructures as a New Class of Continuously Tunable Bright Shortwave Infrared Emitters
المؤلفون: Justin R. Caram, Arundhati Deshmukh, Timothy L. Atallah, Ashley J. Shin, Victoria Vilchez, Sandrine Ithurria, Mikayla L. Sonnleitner, Chengye Huang, Stephanie M. Tenney, Hannah C. Friedman
المصدر: The Journal of Physical Chemistry Letters. 11:3473-3480
بيانات النشر: American Chemical Society (ACS), 2020.
سنة النشر: 2020
مصطلحات موضوعية: Materials science, business.industry, Chalcogenide, chemistry.chemical_element, Heterojunction, Shortwave infrared, Mercury (element), chemistry.chemical_compound, chemistry, Quantum dot, Optoelectronics, Energy transformation, General Materials Science, Physical and Theoretical Chemistry, business, Nanoscopic scale
الوصف: Despite broad applications in imaging, energy conversion, and telecommunications, few nanoscale moieties emit light efficiently in the shortwave infrared (SWIR, 1000-2000 nm or 1.24-0.62 eV). We report quantum-confined mercury chalcogenide (HgX, where X = Se or Te) nanoplatelets (NPLs) can be induced to emit bright (QY30%) and tunable (900-1500+ nm) infrared emission from attached quantum dot (QD) "defect" states. We demonstrate near unity energy transfer from NPL to these QDs, which completely quench NPL emission and emit with a high QY through the SWIR. This QD defect emission is kinetically tunable, enabling controlled midgap emission from NPLs. Spectrally resolved photoluminescence demonstrates energy-dependent lifetimes, with radiative rates 10-20 times faster than those of their PbX analogues in the same spectral window. Coupled with their high quantum yield, midgap emission HgX dots on HgX NPLs provide a potential platform for novel optoelectronics in the SWIR.
تدمد: 1948-7185
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::73c57fed64d2a720cdb18f3097e23fb6
https://doi.org/10.1021/acs.jpclett.0c00958
حقوق: CLOSED
رقم الأكسشن: edsair.doi.dedup.....73c57fed64d2a720cdb18f3097e23fb6
قاعدة البيانات: OpenAIRE