THE REACTION OF [W(PME3)4(ETA-2-CH2PME2)H] WITH CARBON-DIOXIDE AND DIHYDROGEN - CHARACTERIZATION OF [(W(PME3)3(ETA-1-PME2CH2))2(C3H2O6)] USING TWO-DIMENSIONAL NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY
التفاصيل البيبلوغرافية
العنوان:
THE REACTION OF [W(PME3)4(ETA-2-CH2PME2)H] WITH CARBON-DIOXIDE AND DIHYDROGEN - CHARACTERIZATION OF [(W(PME3)3(ETA-1-PME2CH2))2(C3H2O6)] USING TWO-DIMENSIONAL NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY
[W(PMe 3 ) 4 (η 2 -CH 2 PMe 2 )H] reacts with a mixture of CO 2 and H 2 (1/1, 3 atm) at room temperature to give [W(PMe 3 ) 4 H 2 (η 2 -O 2 CO)] and [{W(PMe 3 ) 3 (η 1 -PMe 2 CH 2 )} 2 (C 3 H 2 O 6 )]. [{W(PMe 3 ) 3 (η 1 -PMe 2 CH 2 )} 2 (C 3 H 2 O 6 )] has been characterised using two-dimensional homo- and hetero-nuclear correlation NMR techniques.
