Porous Cobalt Sulfide Selenium Nanorods for Electrochemical Hydrogen Evolution

التفاصيل البيبلوغرافية
العنوان: Porous Cobalt Sulfide Selenium Nanorods for Electrochemical Hydrogen Evolution
المؤلفون: Yingchao Song, Chucai Guo, Zhengtian Shi, Zhiyuan Zhang, Xiangqian Qi, Jianfa Zhang, Zhihong Zhu
المصدر: ACS Omega, Vol 6, Iss 36, Pp 23300-23310 (2021)
ACS Omega
بيانات النشر: American Chemical Society, 2021.
سنة النشر: 2021
مصطلحات موضوعية: Materials science, General Chemical Engineering, chemistry.chemical_element, General Chemistry, Overpotential, Electrochemical energy conversion, Cobalt sulfide, Article, Catalysis, chemistry.chemical_compound, Chemistry, Chemical engineering, chemistry, Electrode, Nanorod, Cobalt, QD1-999, Hydrogen production
الوصف: A key process in electrochemical energy technology is hydrogen evolution reaction (HER). However, its electrochemical properties mainly depend on the catalytic activity of the material itself. Therefore, it is important to find efficient electrocatalysts to realize clean hydrogen production. As a typical kind of catalytic materials, transition metal dichalcogenides (TMCs) play important roles in the field of energy catalysis. As a representative of TMCs, cobalt disulfide (CoS2), recently has raised much research interest owing to its abundant reserves, environmental friendliness, and excellent electrochemical stability. Meanwhile, given the fact that doping is one of the effective methods to improve the electrochemical catalytic property, various means of doping have been researched. Here, we report for the first time that porous-like Se-CoS2-x (or Se:CoS2-x ) nanorod can be facilely synthesized via a controllable two-step strategy. It is demonstrated that doping Se can greatly improve the catalytic performance of CoS2 electrode. The electrode can obtain a current density of 10 mA cm-2 at overpotential of only ∼260 mV. And the current changes with the applied bias voltage in an obvious stepped pattern, in the chronopotential (CP) curve of Se-CoS2-x , indicating its outstanding mass transfer property and mechanical stability.
اللغة: English
تدمد: 2470-1343
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7b52df88b6dd5d17d71ad025f763e8de
https://doaj.org/article/4745f4c83d0f44818276ace107a61454
حقوق: OPEN
رقم الأكسشن: edsair.doi.dedup.....7b52df88b6dd5d17d71ad025f763e8de
قاعدة البيانات: OpenAIRE