Cu(iii )–bis-thiolato complex forms an unusual mono-thiolato Cu(iii )–peroxido adduct
| العنوان: | Cu( |
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| المؤلفون: | Marc Walker, Juliusz A. Wolny, Christina S. Müller, Jane M. Donnelly, Peter B. O’Connor, Frederik Lermyte, Ben Breeze, Peter J. Sadler, Volker Schünemann, Joanna F. Collingwood, Russell J. Needham |
| المصدر: | Chemical Communications. 57:69-72 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | 010405 organic chemistry, Chemistry, Metals and Alloys, chemistry.chemical_element, General Chemistry, 010402 general chemistry, 01 natural sciences, Peroxide, Oxygen, Copper, Catalysis, 3. Good health, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Adduct, chemistry.chemical_compound, X-ray photoelectron spectroscopy, Molybdenum, Polymer chemistry, Materials Chemistry, Ceramics and Composites, Cyclic voltammetry |
| الوصف: | The stable complex [bis(toluene-3,4-dithiolato)copper(iii)][NEt3H] has been synthesised and characterised as a square-planar Cu(iii) complex by X-ray photoelectron spectroscopy, cyclic voltammetry and DFT calculations. Intriguingly, when fragmented in FTICR-MS, an unusual [(toluene-3,4-dithiolate)Cu(iii)(peroxide)]- complex is formed by reaction with oxygen. Natural 1,2-dithiolenes known to bind molybdenum might stabilise Cu(iii) in vivo. |
| تدمد: | 1364-548X 1359-7345 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::83b707283bdea8b3cac4b53fb27f9de1 https://doi.org/10.1039/d0cc06921c |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....83b707283bdea8b3cac4b53fb27f9de1 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1364548X 13597345 |
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