1,1/1,2 Isomerisation in Lewis base adducts of B2cat2
| العنوان: | 1,1/1,2 Isomerisation in Lewis base adducts of B2cat2 |
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| المؤلفون: | Iñigo J. Vitorica-Yrezabal, Michael J. Ingleson, Ian A. Cade, W Y Chau |
| المصدر: | Dalton Transactions. 44:7506-7511 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2015. |
| سنة النشر: | 2015 |
| مصطلحات موضوعية: | Inorganic Chemistry, 010405 organic chemistry, Chemistry, Computational chemistry, Stereochemistry, Lewis acids and bases, 010402 general chemistry, 01 natural sciences, Isomerization, 0104 chemical sciences, Adduct |
| الوصف: | Reaction of bis-catecholatodiborane and 1 or 2 equivalents of 1,5-diazabicyclo[4.3.0]non-5-ene or 4-picoline yields Lewis acid-base adducts. Recrystallisation enabled identification of an unexpected isomerisation from the 1,1-isomer to the 1,2-isomer. This observation was probed computationally with significantly different dipole moments calculated for the two effectively isoenergetic isomeric forms. |
| تدمد: | 1477-9234 1477-9226 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::87fefe29bafcc665572e904b2afcc083 https://doi.org/10.1039/c5dt00645g |
| رقم الأكسشن: | edsair.doi.dedup.....87fefe29bafcc665572e904b2afcc083 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14779234 14779226 |
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