Molecular Permeation in Freestanding Bilayer Silica
| العنوان: | Molecular Permeation in Freestanding Bilayer Silica |
|---|---|
| المؤلفون: | Daniil Naberezhnyi, Lukas Mai, Nassar Doudin, Inga Ennen, Andreas Hütten, Eric I. Altman, Anjana Devi, Petr Dementyev |
| المصدر: | Nano Letters. 22:1287-1293 |
| بيانات النشر: | American Chemical Society (ACS), 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Mechanical Engineering, Graphite, Oxides, General Materials Science, Bioengineering, Gases, General Chemistry, Silicon Dioxide, Condensed Matter Physics, Porosity |
| الوصف: | Graphene and other single-layer structures are pursued as high-flux separation membranes, although imparting porosity endangers their crystalline integrity. In contrast, bilayer silica composed of corner-sharing (SiO4) units is foreseen to be permeable for small molecules due to its intrinsic lattice openings. This study sheds light on the mass transport properties of freestanding 2D SiO2 upon using atomic layer deposition (ALD) to grow large-area films on Au/mica substrates followed by transfer onto Si3N4 windows. Permeation experiments with gaseous and vaporous substances reveal the suspended material to be porous, but the membrane selectivity appears to diverge from the size exclusion principle. Whereas the passage of inert gas molecules is hindered with a permeance below 10-7 mol·s-1·m-2·Pa-1, condensable species like water are found to cross vitreous bilayer silica a thousand times faster in accordance with their superficial affinity. This work paves the way for bilayer oxides to be addressed as inherent 2D membranes. |
| تدمد: | 1530-6992 1530-6984 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8ac5d21fa8553a090e0dba60ae5bbab7 https://doi.org/10.1021/acs.nanolett.1c04535 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....8ac5d21fa8553a090e0dba60ae5bbab7 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15306992 15306984 |
|---|