Access to Fluorenones Using Benzocyclopentynone Surrogate as Partner for the [2 + 2 + 2] Cycloaddition Reaction
| العنوان: | Access to Fluorenones Using Benzocyclopentynone Surrogate as Partner for the [2 + 2 + 2] Cycloaddition Reaction |
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| المؤلفون: | Frédéric Fages, Muriel Amatore, Jean-Luc Parrain, Elena Zaborova, Anne-Doriane Manick, Bruno Salgues, Laurent Commeiras |
| المساهمون: | Institut des Sciences Moléculaires de Marseille (ISM2), Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre Interdisciplinaire de Nanoscience de Marseille (CINaM), Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU), Aix Marseille Université (AMU)-Centre National de la Recherche Scientifique (CNRS) |
| المصدر: | Organic Letters Organic Letters, American Chemical Society, 2020, 22 (5), pp.1894-1898. ⟨10.1021/acs.orglett.0c00235⟩ Organic Letters, 2020, 22 (5), pp.1894-1898. ⟨10.1021/acs.orglett.0c00235⟩ |
| بيانات النشر: | HAL CCSD, 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | 010405 organic chemistry, [CHIM.ORGA]Chemical Sciences/Organic chemistry, Organic Chemistry, chemistry.chemical_element, 010402 general chemistry, 01 natural sciences, Biochemistry, Combinatorial chemistry, Cycloaddition, 0104 chemical sciences, Catalysis, Rhodium, chemistry.chemical_compound, fluorenone, chemistry, Fluorenone, Molecule, Physical and Theoretical Chemistry, alkyne surrogate |
| الوصف: | International audience; A convenient and versatile procedure for the straightforward synthesis of substituted fluorenones as valuable scaffolds is described under rhodium catalysis. The present [2 + 2 + 2] cycloaddition reaction of diynes with 3-acetoxy or-3-alkoxyindenones as surrogates of the highly reactive benzocyclopentynone 2π partner allows the preparation of various fluorenone-type derivatives in good yields and provides an additional and tunable process for the generation of more challenging molecules with application in pharmaceutical, polymer, and material sciences. |
| اللغة: | English |
| تدمد: | 1523-7060 1523-7052 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8eb2204f5e34a01dd09a61a1c63ffaea https://hal.archives-ouvertes.fr/hal-02873529 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....8eb2204f5e34a01dd09a61a1c63ffaea |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15237060 15237052 |
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