Spotting Trends in Organocatalyzed and Other Organomediated (De)polymerizations and Polymer Functionalizations
| العنوان: | Spotting Trends in Organocatalyzed and Other Organomediated (De)polymerizations and Polymer Functionalizations |
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| المؤلفون: | María Valle, Marta Ximenis, Xabier Lopez de Pariza, Julian M. W. Chan, Haritz Sardon |
| المصدر: | Angewandte Chemie International Edition. 61 |
| بيانات النشر: | Wiley, 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Polymers, General Medicine, General Chemistry, Plastics, Catalysis, Polymerization |
| الوصف: | Organocatalysis has evolved into an effective complement to metal- or enzyme-based catalysis in polymerization, polymer functionalization, and depolymerization. The ease of removal and greater sustainability of organocatalysts relative to transition-metal-based ones has spurred development in specialty applications, e.g., medical devices, drug delivery, optoelectronics. Despite this, the use of organocatalysis and other organomediated reactions in polymer chemistry is still rapidly developing, and we envisage their rapidly growing application in nascent areas such as controlled radical polymerization, additive manufacturing, and chemical recycling in the coming years. In this Review, we describe ten trending areas where we anticipate paradigm shifts resulting from novel organocatalysts and other transition-metal-free conditions. We highlight opportunities and challenges and detail how new discoveries could lead to previously inaccessible functional materials and a potentially circular plastics economy. |
| تدمد: | 1521-3773 1433-7851 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::972418bf17df94dcd62121f8794da630 https://doi.org/10.1002/anie.202203043 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....972418bf17df94dcd62121f8794da630 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15213773 14337851 |
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