Recent advances in electrocatalysis with phthalocyanines
| العنوان: | Recent advances in electrocatalysis with phthalocyanines |
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| المؤلفون: | Yihuan Yu, Xinjin Gao, Feng Wang, Zhengping Zhang, Shaoxuan Yang |
| المصدر: | Chemical Society Reviews. 50:12985-13011 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Indoles, Materials science, Oxygen evolution, Structural diversity, Nanotechnology, General Chemistry, Electrochemistry, Electrocatalyst, Porphyrin, Catalysis, Oxygen, chemistry.chemical_compound, chemistry, Chemical stability, Hydrogen, Electrochemical reduction of carbon dioxide |
| الوصف: | Applications of phthalocyanines (Pcs) in electrocatalysis—including the oxygen reduction reaction (ORR), the carbon dioxide reduction reaction (CO2RR), the oxygen evolution reaction (OER), and the hydrogen evolution reaction (HER)—have attracted considerable attention recently. Pcs and their derivatives are more attractive than many other macrocycles as electrocatalysts since, although they are structurally related to natural porphyrin complexes, they offer the advantages of low cost, facile synthesis and good chemical stability. Moreover, their high tailorability and structural diversity mean Pcs have great potential for application in electrochemical devices. Here we review the structure and composition of Pcs, methods of synthesis of Pcs and their analogues, as well as applications of Pc-based heterogeneous electrocatalysts. Optimization strategies for Pc-based materials for electrocatalysis of ORR, CO2RR, OER and HER are proposed, based on the mechanisms of the different electrochemical reactions. We also discuss the structure/composition–catalytic activity relationships for different Pc materials and Pc-based electrocatalysts in order to identify future practical applications. Finally, future opportunities and challenges in the use of molecular Pcs and Pc derivatives as electrocatalysts are discussed. |
| تدمد: | 1460-4744 0306-0012 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9782f44fd18b6bd6d4864a5f8b0c1c9d https://doi.org/10.1039/d0cs01605e |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....9782f44fd18b6bd6d4864a5f8b0c1c9d |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14604744 03060012 |
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