A novel isosteviol‐based bifunctional squaramide organocatalyst for enantioselective Michael addition of acetylacetone to nitroolefins
العنوان: | A novel isosteviol‐based bifunctional squaramide organocatalyst for enantioselective Michael addition of acetylacetone to nitroolefins |
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المؤلفون: | Jing-Chao Tao, Xiaopei Chen, Quanjian Lv, Zhijing Liu, Zhi-Wei Ma, Chuanchuan Wang |
المصدر: | Chirality. 34:77-85 |
بيانات النشر: | Wiley, 2021. |
سنة النشر: | 2021 |
مصطلحات موضوعية: | Pharmacology, Quinine, Acetylacetone, Organic Chemistry, Enantioselective synthesis, Squaramide, Stereoisomerism, Alkenes, Combinatorial chemistry, Catalysis, Analytical Chemistry, Bifunctional catalyst, chemistry.chemical_compound, chemistry, Pentanones, Organocatalysis, Drug Discovery, Michael reaction, Stevioside, Diterpenes, Kaurane, Bifunctional, Spectroscopy |
الوصف: | Chiral amine-squaramide is a kind of effective hydrogen bond donor bifunctional catalyst to promote many asymmetric transformations. In this paper, novel chiral tertiary amine-squaramide derived from the natural product of the stevioside was developed and applied into the asymmetric Michael addition of acetylacetone to nitroolefins. This asymmetric reaction performed well, and a series of enantiomerically enriched compounds were obtained in high yields (up to 96%) with excellent enantioselectivities (up to 99% ee). |
تدمد: | 1520-636X 0899-0042 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9844110e93b21c3adbb06de65e62092a https://doi.org/10.1002/chir.23391 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi.dedup.....9844110e93b21c3adbb06de65e62092a |
قاعدة البيانات: | OpenAIRE |
تدمد: | 1520636X 08990042 |
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