Biphenyl Cyclobutenone Photoelectrocyclizations
| العنوان: | Biphenyl Cyclobutenone Photoelectrocyclizations |
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| المؤلفون: | Xuchen Zhao, Jon D. Rainier, Changqing Song, Changhang Dai, Zach Schwartz |
| المصدر: | J Org Chem |
| بيانات النشر: | American Chemical Society (ACS), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Biphenyl, chemistry.chemical_compound, Chemistry, Biphenyl Compounds, Organic Chemistry, Organic chemistry, Conjugated system, Cyclobutanes, Article |
| الوصف: | In this work, we demonstrate that readily available conjugated bis-aryl cyclobutenones undergo photoelectrocyclization reactions to give the corresponding dihydrophenanthrene cyclobutanones when exposed to 350 nm light, TFA, and TMSCl. We have also found that cyclobutenone electrocyclizations and cycloreversions are in equilibrium. |
| تدمد: | 1520-6904 0022-3263 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9f000a5d955a26682c6ed6cdc48ff27f https://doi.org/10.1021/acs.joc.1c01809 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....9f000a5d955a26682c6ed6cdc48ff27f |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15206904 00223263 |
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