Palladium orthometallated complexes containing acetophenoneoxime: Synthesis, crystal structures and hirshfeld surface analysis
| العنوان: | Palladium orthometallated complexes containing acetophenoneoxime: Synthesis, crystal structures and hirshfeld surface analysis |
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| المؤلفون: | Carolina Barra, Victor M. Deflon, Renan Lira de Farias, Eduardo Tonon de Almeida, Ronan F.F. De Souza, Adelino Vieira de Godoy Netto, Fillipe V. Rocha, Gabriela F. Bozza, Antonio Eduardo Mauro |
| المساهمون: | Universidade Estadual Paulista (Unesp), Universidade Federal de São Carlos (UFSCar), Ciência e Tecnologia de São Paulo, Universidade de São Paulo (USP), Instituto de Química |
| المصدر: | Scopus Repositório Institucional da UNESP Universidade Estadual Paulista (UNESP) instacron:UNESP Repositório Institucional da USP (Biblioteca Digital da Produção Intelectual) Universidade de São Paulo (USP) instacron:USP |
| بيانات النشر: | Elsevier BV, 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | Tris, 010405 organic chemistry, Crystal structure, Organic Chemistry, Intermolecular force, chemistry.chemical_element, Type (model theory), PALÁDIO, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Analytical Chemistry, Inorganic Chemistry, Crystal, Crystallography, chemistry.chemical_compound, chemistry, Oximes, Hirshfeld surface analysis, Cyclopalladated compounds, Spectroscopy, Phosphine, Palladium |
| الوصف: | Made available in DSpace on 2019-10-06T16:48:01Z (GMT). No. of bitstreams: 0 Previous issue date: 2019-01-05 Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) The bridge-splitting reaction between [Pd(C2,N-aphox)(μ-Cl)]2 and phosphines (L), in a 1:2 ratio, yielded neutral mononuclear cyclopalladated compounds of the type [PdCl(C2,N-aphox)(L)] {aphox = acetophenoneoxime; L = triphenylphosphine (1), tris(4-fluorophenyl)phosphine (2), tri-cyclohexylphosphine (3), diphenyl(p-toluyl)phosphine (4), tris-(4-methoxyphenyl)phosphine (5) and tri(p-toluyl)phosphine (6)}. The compounds were characterized by elemental analyses, IR and 1H-, 13C{1H}- and 31P{1H}-NMR spectroscopies. The crystal and molecular structures of 1–5 were determined by single-crystal X-ray diffraction. After that, the Hirshfeld surface calculations were carried out to explore the nature and major contributions of different intermolecular contacts towards crystal packing stability. UNESP - Univ Estadual Paulista Institute of Chemistry UFSCar Univ Federal de São Carlos Departamento de Química Instituto Federal de Educação Ciência e Tecnologia de São Paulo, Campus Araraquara Instituto de Química de São Carlos Universidade de São Paulo UNIFAL - MG - Univ Federal de Alfenas Instituto de Química UNESP - Univ Estadual Paulista Institute of Chemistry FAPESP: 2012/15486-3 FAPESP: 2014/11340-0 FAPESP: 2016/17711-5 CNPq: 422105/2016-3 |
| تدمد: | 0022-2860 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a4d694fa8baea43aabc4886ac46d8063 https://doi.org/10.1016/j.molstruc.2018.07.108 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....a4d694fa8baea43aabc4886ac46d8063 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 00222860 |
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