Total synthesis of C37 alken-2-one temperature geomarkers
| العنوان: | Total synthesis of C37 alken-2-one temperature geomarkers |
|---|---|
| المؤلفون: | Anna Alcaide, Carme Serra, Juanlo Catena, Lourdes Muñoz, Amadeu Llebaria |
| بيانات النشر: | Elsevier, 2023. |
| سنة النشر: | 2023 |
| مصطلحات موضوعية: | Organic Chemistry, Drug Discovery, Paleoclimate indicators, Total synthesis, Biochemistry, Ensure healthy lives and promote well-being for all at all ages, Long-chain alkenones |
| الوصف: | The total synthesis of the natural (8E,15E,22E)-heptatriaconta-8,15,22-trien-2-one and (15E,22E)-heptatriaconta-15,22-dien-2-one is reported. Our synthesis involved a modular and convergent approach, based on the copper-catalyzed addition of Grignard reagents to allylic olefins. The obtention of these methyl ketones is an important asset for the use of these compounds as analytical patterns with application in Earth sciences. We gratefully acknowledge the Geochemistry and Pollution Research Group from the Institute of Environmental Assessment and Water Research (IDAEA-CSIC) and CSIC (201980E011) for financial support. |
| اللغة: | English |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b055a852330382598b7082c94fa54b5d http://hdl.handle.net/10261/329463 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....b055a852330382598b7082c94fa54b5d |
| قاعدة البيانات: | OpenAIRE |
| الوصف غير متاح. |