Quantification of Carbonyl Compounds Generated from Ozone-Based Food Colorants Decomposition Using On-Fiber Derivatization-SPME-GC-MS
| العنوان: | Quantification of Carbonyl Compounds Generated from Ozone-Based Food Colorants Decomposition Using On-Fiber Derivatization-SPME-GC-MS |
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| المؤلفون: | H. Duygu Ozsoy, Jacek A. Koziel, J. (Hans) van Leeuwen, Lingshuang Cai, W. W. Zhu |
| المصدر: | Chromatography, Vol 2, Iss 1, Pp 1-18 (2014) Chromatography Volume 2 Issue 1 Pages 1-18 |
| بيانات النشر: | MDPI AG, 2014. |
| سنة النشر: | 2014 |
| مصطلحات موضوعية: | Detection limit, Ozone, Chromatography, Chemistry, Pulp (paper), on-fiber derivatization SPME-gas chromatography-mass spectrometry, fruit pulp, Spme gc ms, General Medicine, PFBHA, engineering.material, Mass spectrometry, Hexanal, ozone-based decolorization, Benzaldehyde, lcsh:Chemistry, chemistry.chemical_compound, carbonyl compounds, lcsh:QD1-999, processed aqueous solution/suspension, engineering, Derivatization |
| الوصف: | Fruit leathers (FLs) production produces some not-to-specification material, which contains valuable ingredients like fruit pulp, sugars and acidulates. Recovery of FL for product recycling requires decolorization. In earlier research, we proved the efficiency of an ozone-based decolorization process however, it produces carbonyls as major byproducts, which could be of concern. A headspace solid-phase microextraction with on-fiber derivatization followed by gas chromatography-mass spectrometry was developed for 10 carbonyls analysis in ozonated FL solution/suspension. Effects of dopant concentration, derivatization temperature and time were studied. The adapted method was used to analyze ozonated FL solution/suspension samples. Dopant concentration and derivatization temperature were optimized to 17 mg/mL and 60 °C, respectively. Competitive extraction was studied, and 5 s extraction time was used to avoid non-linear derivatization of 2-furfural. The detection limits (LODs) for target carbonyls ranged from 0.016 and 0.030 µg/L. A much lower LOD (0.016 ppb) for 2-furfural was achieved compared with 6 and 35 ppb in previous studies. Analysis results confirmed the robustness of the adapted method for quantification of carbonyls in recycled process water treated with ozone-based decolorization. Ethanal, hexanal, 2-furfural, and benzaldehyde were identified as byproducts of known toxicity but all found below levels for concern. |
| وصف الملف: | application/pdf |
| اللغة: | English |
| تدمد: | 2227-9075 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bb29961df2b536c6b8ba69d309a37904 http://www.mdpi.com/2227-9075/2/1/1 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....bb29961df2b536c6b8ba69d309a37904 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 22279075 |
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