Hydrothermal Synthesis, Structures, and Physical Properties of Four New Flexible Multicarboxylate Ligands-Based Compounds
| العنوان: | Hydrothermal Synthesis, Structures, and Physical Properties of Four New Flexible Multicarboxylate Ligands-Based Compounds |
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| المؤلفون: | Stuart Robert Batten, You Song, Yi-Zhi Li, Zhaorui Pan, Zi-Jian Guo, Tian-Wei Wang, Hegen Zheng |
| المصدر: | Inorganic Chemistry. 47:9528-9536 |
| بيانات النشر: | American Chemical Society (ACS), 2008. |
| سنة النشر: | 2008 |
| مصطلحات موضوعية: | Hydrogen bond, Stereochemistry, Ligand, Supramolecular chemistry, Crystal structure, Inorganic Chemistry, chemistry.chemical_compound, Crystallography, chemistry, Hydrothermal synthesis, Metal-organic framework, Physical and Theoretical Chemistry, Methylene, Isostructural |
| الوصف: | Four new compounds of partially or wholly deprotonated 5,5'-(1,4-phenylenebis(methylene))bis(oxy)diisophthalic acid (H4L1) and 5,5'-(1,3-phenylenebis(methylene))bis(oxy)diisophthalic acid (H4L2), namely {[Co(L1)0.5] x (H2O)2}n (1), {[Mn(L1)0.5] x (H2O)2}n (2), {[Cu(H2L1)](mu2-bipy)}n (bipy = 4, 4'-bipyridyl) (3), and {[Zn2(L2)] x H2O}n (4) were synthesized in the presence or absence of auxiliary bipy ligand. Their structures have been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectra, and thermogravimetric analysis. Compounds 1 and 2 are isostructural and possess three-dimensional (3D) networks. In compound 3, multicarboxylate ligands and bipy ligands link Cu centers to generate a two-dimensional (2D) sheet structure which is further connected by intermolecular hydrogen bonds to form a 3D supramolecular structure. In compound 4, the Zn centers are connected by L2(4-) anions to generate a 3D framework. Magnetic susceptibility measurements indicate that compounds 1 and 2 exhibit antiferromagnetic coupling between adjacent Co(II) ions and Mn(II) ions. The photoluminescent properties of the free 4L1 and H4L2 ligands and compound 4 have been studied in the solid state at room temperature. Both ligands and compound 4 exhibit strong violet emissions. Compared with the fluorescent emission of the ligand, the emission of 4 is red-shifted and enhanced. |
| تدمد: | 1520-510X 0020-1669 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bb8dcf4eafc036fa4e6ce974cdcb668e https://doi.org/10.1021/ic801221r |
| رقم الأكسشن: | edsair.doi.dedup.....bb8dcf4eafc036fa4e6ce974cdcb668e |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 1520510X 00201669 |
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