To describe the angular distribution for a group-to-group neutron scattering event, the coefficients of a truncated Legendre polynomial are usually used in the multigroup cross section. However, the truncated expansion can caused negative values of a probability density function (PDF) in some scattering angles. In this study, the PDF of scattering angles is calculated using the maximum entropy method to avoid the negative probabilities of some scattering angles and the multigroup cross section library in ACE format is generated. The multigroup cross section library is verified by the computation of RBEC-M benchmark using RMC. The differences between two methods generating scattering data, the maximum entropy method and discrete angle method, are also discussed. The calculation results using multigroup cross section library in ACE format are well good agreement with the results of benchmark report. It shows that multigroup cross section library including the scattering angle data computed by the maximum entropy method is corrected and can be used for Monte Carlo calculation.
