Electrochemically active sites inside crystalline porous materials for energy storage and conversion
| العنوان: | Electrochemically active sites inside crystalline porous materials for energy storage and conversion |
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| المؤلفون: | Wei Shuang, Xian-He Bu, Yunhua Xu, Ming Zhong, Lingjun Kong |
| المصدر: | Chemical Society Reviews. 49:2378-2407 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | Materials science, Template, Metal ions in aqueous solution, Rational design, Water splitting, Nanotechnology, General Chemistry, Crystal structure, Porous medium, Electrochemistry, Energy storage |
| الوصف: | The design and development of crystalline porous materials (CPMs), including metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs), have been subjects of extensive study due to their regular crystalline lattices and well-defined pore structures. In recent times, an enormous amount of research effort has gone into using CPMs as sacrificial templates to fabricate electrochemically functional materials. The inherently electrochemically active sites inside CPMs are notably abundant and being explored with respect to electrochemical reactions. In this review, electrochemically active sites and the space around them (metal ions, ligands, crystal structures, pores, and morphologies) inside CPMs are the focus and recent progress in the fields of metal-ion batteries, metal-air batteries, water splitting, and other related electrochemical devices has been summarized. Overall, this review provides guidance on the preparation of electroactive CPMs via rational design and modulation of active sites such as redox-active metal clusters and organic ligands, and the space around the electrochemically active sites, and their applications in electrochemical energy storage and conversion systems. |
| تدمد: | 1460-4744 0306-0012 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ca2c1ee06802f91960b1f9450c6c6e2e https://doi.org/10.1039/c9cs00880b |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....ca2c1ee06802f91960b1f9450c6c6e2e |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14604744 03060012 |
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