Enantioselective Synthesis of Both Axially and Planar Chiral Ferrocenes via Axial-to-Planar Diastereoinduction
| العنوان: | Enantioselective Synthesis of Both Axially and Planar Chiral Ferrocenes via Axial-to-Planar Diastereoinduction |
|---|---|
| المؤلفون: | Yang An, Xiao-Yan Zhang, Ya-Nan Ding, Yuke Li, Xue-Yuan Liu, Yong-Min Liang |
| المصدر: | Organic Letters. 24:7294-7299 |
| بيانات النشر: | American Chemical Society (ACS), 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Organic Chemistry, Physical and Theoretical Chemistry, Biochemistry |
| الوصف: | Ferrocenes with planar chirality have emerged as an important class of scaffolds for ligands in asymmetric catalysis; however, ferrocene molecules with polychiral structures have not been well explored. Herein, both axially and planar chiral ferrocenes were synthesized via palladium/chiral norbornene cooperative catalysis and axial-to-planar diastereoinduction. In this work, chiral norbornene was used to stereoselectively control the aromatic axial chirality, and further selectivity induced C(sp |
| تدمد: | 1523-7052 1523-7060 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ccfcfadaf61c158273d4715001c06fb7 https://doi.org/10.1021/acs.orglett.2c02707 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....ccfcfadaf61c158273d4715001c06fb7 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15237052 15237060 |
|---|