Spectroscopic ellipsometry study of Cu2ZnSn(SxSe1-x)4 bulk polycrystals
العنوان: | Spectroscopic ellipsometry study of Cu2ZnSn(SxSe1-x)4 bulk polycrystals |
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المؤلفون: | Rosalía Serna, A. Nateprov, Ivan A. Victorov, Sergiu Levcenko, Raquel Caballero, José Manuel Merino, Máximo León, Ernest Arushanov, E. Hajdeu-Chicarosh, Maxim Guc, I. V. Bodnar |
المساهمون: | European Commission, Ministerio de Economía y Competitividad (España), Ministerio de Ciencia, Innovación y Universidades (España), Generalitat de Catalunya |
المصدر: | Digital.CSIC. Repositorio Institucional del CSIC instname Journal of Alloys and Compounds |
بيانات النشر: | Elsevier, 2020. |
سنة النشر: | 2020 |
مصطلحات موضوعية: | High energy, Polycrystals, Materials science, Analytical chemistry, Optical spectroscopy, 02 engineering and technology, engineering.material, 010402 general chemistry, 7. Clean energy, 01 natural sciences, symbols.namesake, Ellipsometry, Materials Chemistry, Kesterite, Spectroscopy, Semiconductor compounds, Kesterites, Range (particle radiation), Mechanical Engineering, Metals and Alloys, Function (mathematics), 021001 nanoscience & nanotechnology, 0104 chemical sciences, Mechanics of Materials, Raman spectroscopy, engineering, symbols, Spectroscopic ellipsometry, 0210 nano-technology |
الوصف: | 6 pags., 4 figs., 2 tabs. The pseudo dielectric function of CuZnSn(SSe) [x = 0.35, 0.62, 0.81] bulk polycrystals is determined over the range 1.1–4.6 eV at room temperature from the analysis of spectroscopic ellipsometry data using the Adachi model. From the analysis, the lowest E transition and high energy E and E transitions are clearly identified, and used to follow the evolution of the pseudo dielectric function as a function of the composition. It is shown that the fundamental E and high energy E transitions can be tuned by increasing the sulfur content over a range of 0.3 eV. These results show the potential of the kesterite compounds for the design of efficient tailored photovoltaic solar cells. The research leading to the presented results was partially supported by the European Project INFINITE-CELL (Ref. H2020-MSCA-RISE-2017-777968, 2017e2021,www.infinitecell.eu) andthe Spanish MINECO Projects“WINCOST”(ENE2016-80788-C5-2-R) and“SENSIL”RTI2018-096498-B-I00 (MCIU/AEI/FEDER, UE).The authors from the Institute of Applied Physics appreciate the financial support from the Bilateral Project No. ANCD19.80013.16.02.01F/BL and from the Institutional Project No. CSSDT15.817.02.04A. Authors from IREC belong to the M-2E (Electronic Materials for Energy) Consolidated Research Group and the XaR-MAE Network of Excellence on Materials for Energy of the“Generalitat de Catalunya”. M. Guc thanks Generalitat de Catalunya for the TECNIO springþ fellowship (TECSPR18-1-0048). |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d4e63f923aa17e55599a764b58aec7b5 http://hdl.handle.net/10261/223263 |
حقوق: | OPEN |
رقم الأكسشن: | edsair.doi.dedup.....d4e63f923aa17e55599a764b58aec7b5 |
قاعدة البيانات: | OpenAIRE |
الوصف غير متاح. |