Off-critical wetting layer divergence at the liquid/vapor interface of binary liquid mixtures
| العنوان: | Off-critical wetting layer divergence at the liquid/vapor interface of binary liquid mixtures |
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| المؤلفون: | J. Charles Williamson, Emily E. Weatherford, Makayla M. DenBeste, K. Caroline Riley, Estella F. Yee, Sawyer T. Rogers, Clara A. Tibbetts |
| المصدر: | The Journal of Chemical Physics. 157:084504 |
| بيانات النشر: | AIP Publishing, 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | General Physics and Astronomy, Physical and Theoretical Chemistry |
| الوصف: | Surface wetting phenomena impact chemistry, physics, biology, and engineering. The wetting behaviors of partially miscible binary liquid systems are especially complex. Here, we report evidence of universal behavior in the divergence of wetting layer growth at liquid–vapor interfaces of the cyclohexane + aniline, hexane + o-toluidine, and methanol + carbon disulfide systems. Layer growth on the micron scale was followed using visible light scattering from stirred samples. The layer thicknesses were found to diverge with decreasing temperature when coexistence was approached from the one-phase region, but only for solutions richer in the higher density/higher surface tension component. The onset of divergence was |
| تدمد: | 1089-7690 0021-9606 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::de3cc397a69fec6ea44768cc6158b41d https://doi.org/10.1063/5.0105690 |
| رقم الأكسشن: | edsair.doi.dedup.....de3cc397a69fec6ea44768cc6158b41d |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Scitation. | تدمد: | 10897690 00219606 |
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