Copper-Catalyzed Amination of Primary Benzylic C−H Bonds with Primary and Secondary Sulfonamides
| العنوان: | Copper-Catalyzed Amination of Primary Benzylic C−H Bonds with Primary and Secondary Sulfonamides |
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| المؤلفون: | Hope Fan, David A. Powell |
| المصدر: | The Journal of Organic Chemistry. 75:2726-2729 |
| بيانات النشر: | American Chemical Society (ACS), 2010. |
| سنة النشر: | 2010 |
| مصطلحات موضوعية: | Sulfonamides, Primary (chemistry), Chemistry, Organic Chemistry, Benzene, Medicinal chemistry, Carbon, Catalysis, Copper catalyzed, Organic chemistry, Selectivity, Copper, Amination, Hydrogen |
| الوصف: | A room-temperature, copper-catalyzed amination of primary benzylic C-H bonds with primary and secondary sulfonamides is described. The reaction is applicable to the coupling of a range of primary and secondary benzylic hydrocarbons with a diverse set of sulfonamides and is tolerant of substitution on both coupling partners. Factors which influence the selectivity of C-H functionalization between primary and secondary sites are examined. |
| تدمد: | 1520-6904 0022-3263 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ded154dc0a7825918be2e14a4909590d https://doi.org/10.1021/jo100197r |
| رقم الأكسشن: | edsair.doi.dedup.....ded154dc0a7825918be2e14a4909590d |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15206904 00223263 |
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