Linking viscosity to equations of state using residual entropy scaling theory

التفاصيل البيبلوغرافية
العنوان: Linking viscosity to equations of state using residual entropy scaling theory
المؤلفون: Xiaoxian Yang, Xiong Xiao, Monika Thol, Markus Richter, Ian H. Bell
بيانات النشر: Research Square Platform LLC, 2022.
سنة النشر: 2022
مصطلحات موضوعية: Condensed Matter Physics
الوصف: In our previous work (J Chem Eng Data 2021, 66(3):1385–1398), a residual entropy scaling (RES) approach was developed to link viscosity to residual entropy [a thermodynamic property calculated with an equation of state (EoS)] using a simple polynomial equation for refrigerants. Here, we present an extension of this approach to a much wider range of fluids: all pure fluids and their mixtures whose reference EoS and experimental viscosity data are available. A total of 84 877 experimental points for 124 pure fluids and 351 mixtures are collected from 1846 references. The investigated pure fluids contain a wide variety of fluids from light gases with quantum effects at low temperatures to dense fluids and fluids with strong intermolecular association. More than 68.2 % (corresponding to the standard deviation) of the evaluated experimental data agree with the RES model within 3.2 % and 8.0 % for pure fluids and mixtures, respectively. Compared to the recommended models implemented in the REFPROP 10.0 software (the state-of-the-art for thermophysical property calculation), if the dilute gas viscosity is calculated in the same way, our RES approach yields similar statistical agreement with the experimental data while having a much simpler formulation and fewer parameters. To use our RES model, a software package written in Python is provided in the supporting information. Graphical Abstract
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e352ec857b6964e79f9f127f2514fbbf
https://doi.org/10.21203/rs.3.rs-1977918/v1
حقوق: OPEN
رقم الأكسشن: edsair.doi.dedup.....e352ec857b6964e79f9f127f2514fbbf
قاعدة البيانات: OpenAIRE