Isoselenocarbonyl complexes
| العنوان: | Isoselenocarbonyl complexes |
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| المؤلفون: | Ian A. Cade, Anthony F. Hill, Caitlin M. A. McQueen |
| المصدر: | Dalton Transactions. 48:2000-2012 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | Inorganic Chemistry, 010405 organic chemistry, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, 3. Good health |
| الوصف: | The salt elimination reactions of [NEt4][Mo(CSe)(CO)2(Tp*)] ([NEt4][2], Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with a range of metal halide complexes (ClMLn) have been investigated as a possible route to isoselenocarbonyl complexes [Mo(CSeMLn)(CO)2(Tp*)]. Thus the reactions of [NEt4][2] with [RuCl(L)2(η-C5R5)] provide molybdenum-ruthenium derivatives [Mo{CSeRu(L)2(η-C5R5)}(CO)2(Tp*)] (L = PPh3, R = H 4, L = CO, R = Me 5), both of which were structurally characterised. The molybdenum-iron derivative [Mo{CSeFe(CO)2(η-C5H5)}(CO)2(Tp*)] (6) was obtained from [NEt4][2] and [FeCl(CO)2(η-C5H5)] however its formulation currently rests on spectroscopic and microanalytical data. The reaction of [NEt4][2] with [RuH(NCMe)(CO)2(PPh3)2]PF6 affords the structurally characterised hydrido-isoselenocarbonyl complex [Mo{CSeRuH(CO)2(PPh3)2}(CO)2(Tp*)] (7) with no indication of coupling of the hydride and selenocarbonyl ligand. |
| تدمد: | 1477-9234 1477-9226 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e3b25fbc7d97d3a87e0b2e82d3ffc4ad https://doi.org/10.1039/c8dt04947e |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....e3b25fbc7d97d3a87e0b2e82d3ffc4ad |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14779234 14779226 |
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