Ultra-short helix pitch and spiral ordering in cholesteric liquid crystal revealed by resonant soft X-ray scattering

التفاصيل البيبلوغرافية
العنوان: Ultra-short helix pitch and spiral ordering in cholesteric liquid crystal revealed by resonant soft X-ray scattering
المؤلفون: Mattis Fondell, Ladislav Fekete, Alevtina Smekhova, Radu Abrudan, Vladimíra Novotná, Vera Hamplova, Boris I. Ostrovskii
المصدر: Soft matter. 18(1)
سنة النشر: 2021
مصطلحات موضوعية: Materials science, Absorption spectroscopy, K-edge, Scattering, Cholesteric liquid crystal, Liquid crystal, Phase (matter), Isotropy, Helix, Large scale facilities for research with photons neutrons and ions, General Chemistry, Condensed Matter Physics, Molecular physics
الوصف: The spontaneous formation of chiral structures offers a variety of liquid crystals LC phases that could be further tailored for practical applications. In our work, the characteristic features of spiral ordering in the cholesteric phase of EZL10 10 LC were evaluated. To disclose resonant reflections related to a nanoscale helix pitch, resonant soft X ray scattering at the carbon K edge was employed. The angular positions of the observed element specific scattering peaks reveal a half pitch of the spiral ordering p 2 amp; 8776; 52 nm indicating the full pitch of about 104 nm at room temperature. The broadening of the peaks points to a presence of coherently scattering finite size domains formed by cholesteric spirals with lengths of about five pitches. No scattering peaks were detectable in the EZL10 10 isotropic phase at higher temperatures. The characteristic lengths extracted from the resonant soft X ray scattering experiment agree well with the periodicity of the surface fingerprint pattern observed in the EZL10 10 cholesteric phase by means of atomic force microscopy. The stability of LC molecules under the incident beam was proven by X ray absorption spectroscopy in transmission geometry
وصف الملف: application/pdf
تدمد: 1744-6848
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e7ba0a18d83655b7e4a4cb6769c6af28
https://pubmed.ncbi.nlm.nih.gov/34870645
حقوق: OPEN
رقم الأكسشن: edsair.doi.dedup.....e7ba0a18d83655b7e4a4cb6769c6af28
قاعدة البيانات: OpenAIRE