Functionalized Magnetic Nanoparticles as Catalysts for Enantioselective Henry Reaction

التفاصيل البيبلوغرافية
العنوان: Functionalized Magnetic Nanoparticles as Catalysts for Enantioselective Henry Reaction
المؤلفون: Ludovica Primitivo, Marzia Oneto Domenici, Lorenza Suber, Ilaria Ben Romdan, Martina De Angelis, Alessandra Ricelli, Giuliana Righi, Andrea Mastrodonato, Carla Sappino, Luciano Pilloni, Chiara Tatangelo
المساهمون: Sappino, C., Primitivo, L., De Angelis, M., Domenici, M. O., Mastrodonato, A., Romdan, I. B., Tatangelo, C., Suber, L., Pilloni, L., Ricelli, A., Righi, G.
المصدر: ACS Omega
ACS Omega, Vol 4, Iss 26, Pp 21809-21817 (2019)
بيانات النشر: American Chemical Society (ACS), 2019.
سنة النشر: 2019
مصطلحات موضوعية: Nitroaldol reaction, General Chemical Engineering, Enantioselective synthesis, Nanoparticle, Alcohol, General Chemistry, Diethylzinc, Combinatorial chemistry, Article, Catalysis, Chemistry, chemistry.chemical_compound, chemistry, Magnetic nanoparticles, asymmetric catalysis, magnetic nanoparticles, Henry reaction, QD1-999, Superparamagnetism
الوصف: With the aim to easily recover and reuse the catalyst, an efficient amino alcohol catalyst previously tested in the asymmetric addition of diethylzinc to several aromatic aldehydes has been immobilized on proper functionalized superparamagnetic core-shell magnetite-silica nanoparticles and employed in the Henry reaction in the semi-homogeneous phase. The nanocatalyst exhibits a promising catalytic activity that remains unchanged in the three catalytic cycles performed. The results prove that highly efficient catalysts, by being immobilized on suitable magnetic nanosupports, can be easily recovered and reused, maintaining their catalytic behavior.
تدمد: 2470-1343
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e974533e180317f2b847174bbda3865d
https://doi.org/10.1021/acsomega.9b02683
حقوق: OPEN
رقم الأكسشن: edsair.doi.dedup.....e974533e180317f2b847174bbda3865d
قاعدة البيانات: OpenAIRE