ACTIVATION OF SP3 CARBON-HYDROGEN BONDS OF ALKYLBENZENES BY RHENIUM FORMING BINUCLEAR MU-ARYLIDENE DERIVATIVES
| العنوان: | ACTIVATION OF SP3 CARBON-HYDROGEN BONDS OF ALKYLBENZENES BY RHENIUM FORMING BINUCLEAR MU-ARYLIDENE DERIVATIVES |
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| المؤلفون: | Andrew E. Derome, F. Geoffrey N. Cloke, Malcolm L. H. Green, Dermot O'Hare |
| سنة النشر: | 2016 |
| مصطلحات موضوعية: | Hydrogen bond, Stereochemistry, chemistry.chemical_element, Rhenium, p-Xylene, Medicinal chemistry, Ethylbenzene, Toluene, chemistry.chemical_compound, chemistry, Molecular Medicine, Alkylbenzenes, Carbene, Mesitylene |
| الوصف: | Co-condensation of rhenium atoms with the arenas 1,3,5-R3C6H3, R3= MeH2 or Me3, or 1,4-Me2C6H4 gives the compounds [{(η-arene)Re}2(µ-CHR′)(µ-H)2], where R′= Ph, 3,5-Me2C6H3, or 4-MeC6H4 respectively, which contain a µ-arylidene group; the structurally related compounds [{(η-arene)Re}2(µ-CR1R2)(µ-H)2], where R1,R2= Me, Ph or H, CH2Ph, are formed from rhenium atoms and ethylbenzene. |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::edb34b5f8bbe5938ab854d6e990f3304 https://doi.org/10.1039/c39830001312 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....edb34b5f8bbe5938ab854d6e990f3304 |
| قاعدة البيانات: | OpenAIRE |
| الوصف غير متاح. |