A Synthesis of an Ionomycin Calcium Complex
| العنوان: | A Synthesis of an Ionomycin Calcium Complex |
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| المؤلفون: | Stephen M. McAteer, Stefan Schunk, Thomas N. Snaddon, Philip J. Kocienski, Yingfa Li, Zhanghua Gao, John P. Cooksey, Eddy M. E. Viseux |
| المصدر: | Angewandte Chemie International Edition. 48:5022-5025 |
| بيانات النشر: | Wiley, 2009. |
| سنة النشر: | 2009 |
| مصطلحات موضوعية: | Stereochemistry, Ionomycin, Allene, Enantioselective synthesis, Total synthesis, chemistry.chemical_element, Stereoisomerism, General Chemistry, Calcium, Catalysis, Anti-Bacterial Agents, chemistry.chemical_compound, Cycloisomerization, chemistry, Cyclization, Stereoselectivity, Gold |
| الوصف: | Caught in the middle: The ionomycin calcium complex (see structure; O red, Ca green) was the target of an approach featuring the efficient asymmetric synthesis of an allene by a copper(I)-mediated anti-selective S(N)2' reaction, a highly stereoselective gold(III)-catalyzed cycloisomerization of an alpha-hydroxyallene, and a Rh-catalyzed rearrangement of an alpha-diazo-beta-hydroxyketone. |
| تدمد: | 1521-3773 1433-7851 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::edc223ddc5141c7f8a75ed539ceff2d4 https://doi.org/10.1002/anie.200901608 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....edc223ddc5141c7f8a75ed539ceff2d4 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15213773 14337851 |
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