Ultra-fast covalent molecular printing on cellulose paper by photo-strain-triggered click ligation: UV LED versus laser irradiations

التفاصيل البيبلوغرافية
العنوان: Ultra-fast covalent molecular printing on cellulose paper by photo-strain-triggered click ligation: UV LED versus laser irradiations
المؤلفون: Denis Gindre, Marie Denis, François-Xavier Felpin
المساهمون: Chimie Et Interdisciplinarité : Synthèse, Analyse, Modélisation (CEISAM), Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), MOLTECH-Anjou, Université d'Angers (UA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
المصدر: Journal of Materials Science
Journal of Materials Science, Springer Verlag, 2020, ⟨10.1007/s10853-020-05585-4⟩
بيانات النشر: HAL CCSD, 2020.
سنة النشر: 2020
مصطلحات موضوعية: Materials science, Strain (chemistry), Mechanical Engineering, Diffusion, Resolution (electron density), 02 engineering and technology, [CHIM.MATE]Chemical Sciences/Material chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, Laser, Photochemistry, 01 natural sciences, 0104 chemical sciences, law.invention, chemistry.chemical_compound, chemistry, Mechanics of Materials, law, Covalent bond, General Materials Science, Cyclopropenone, Cellulose, 0210 nano-technology, Layer (electronics), ComputingMilieux_MISCELLANEOUS
الوصف: The use of cyclopropenone derivatives as latent photo-released strained cyclic alkynes is reported for the covalent printing of complex patterns on cellulose paper. Two different approaches using either a UV LED or a laser as light irradiation source are discussed. While the high intensity of the laser damages the grafted molecular layer, the use of a simple UV LED allows the printing in only 8 min at room temperature with a good resolution at the micrometer scale with negligible diffusion. The validity of this strategy is demonstrated through the sequential printing of a QR code and a logo on the same paper sheet.
اللغة: English
تدمد: 0022-2461
1573-4803
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb97729efa7e4aec2930d1f6b5bd0e5b
https://hal.univ-angers.fr/hal-03054333
حقوق: CLOSED
رقم الأكسشن: edsair.doi.dedup.....fb97729efa7e4aec2930d1f6b5bd0e5b
قاعدة البيانات: OpenAIRE