Aerobic α-hydroxylation of 2-Me-1-tetralone in 1-alkyl-3-methylimidazolium ionic liquids
| العنوان: | Aerobic α-hydroxylation of 2-Me-1-tetralone in 1-alkyl-3-methylimidazolium ionic liquids |
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| المؤلفون: | Yongtao Wang, Zeyu Wen, Jia Yao, Haoran Li, Yue Zhang, Xinyu Wang |
| المصدر: | Physical Chemistry Chemical Physics. 23:5864-5869 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | chemistry.chemical_classification, 1-Tetralone, 010405 organic chemistry, General Physics and Astronomy, Substrate (chemistry), Nuclear Overhauser effect, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Reaction rate, chemistry.chemical_compound, chemistry, Ionic liquid, Organic chemistry, Physical and Theoretical Chemistry, Solvent effects, Two-dimensional nuclear magnetic resonance spectroscopy, Alkyl |
| الوصف: | The aerobic α-hydroxylation of 2-Me-1-tetralone was investigated in imidazol-based ionic liquids (ILs), where reactions in 1-alkyl-3-methylimidazolium tetrafluoroborates were found to generate considerable products. By correlating the conversion at 2 h with viscosity, relative permittivity and the ET(30) value of ILs, we found that the local polarity in ILs represented by the ET(30) value or the chemical shift of α-proton at the substrate was the critical factor influencing the reaction rate. Furthermore, two-dimensional nuclear Overhauser effect spectroscopy (2D NOESY) was used to characterize the distribution of 2-Me-1-tetralone in ILs. As a result, the mesoscopic structures in ILs were recommended to have crucial influences on the distribution of the substrate in ILs, and the caused local polarity could affect the activation of 2-Me-1-tetralone. These findings revealed the solvent effects of ILs with different structures on the α-hydroxylation of 2-Me-1-tetralone, and may encourage the explorations of more types of aerobic oxidations in ILs. |
| تدمد: | 1463-9084 1463-9076 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fffe9b537b5237720eb3aa83fc203cbc https://doi.org/10.1039/d0cp06047j |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....fffe9b537b5237720eb3aa83fc203cbc |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14639084 14639076 |
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