Synthesis, isolation of isomers and spectroscopic characterization of 3- and 4-2-[(2-vinylphenyl)ethenyl]pyridine

التفاصيل البيبلوغرافية
العنوان: Synthesis, isolation of isomers and spectroscopic characterization of 3- and 4-2-[(2-vinylphenyl)ethenyl]pyridine
المؤلفون: Cuculić, Leo
المساهمون: Škorić, Irena
بيانات النشر: Sveučilište u Zagrebu. Fakultet kemijskog inženjerstva i tehnologije., 2015.
سنة النشر: 2015
مصطلحات موضوعية: piridin, pyridine, spectroscopy, PRIRODNE ZNANOSTI. Kemija. Organska kemija, NATURAL SCIENCES. Chemistry. Organic Chemistry, spektroskopija, Wittig reaction, o-divinylbenzene, Wittigova reakcija, o-divinilbenzen
الوصف: U cilju nastavka proučavanja utjecaja heterocikličke jezgre na fotokemijsko ponašanje supstituiranih o-divinilbenzena razvijena je sinteza novih supstituiranih o-divinilbenzena s piridinskom jezgrom. Wittigovom reakcijom sintetizirani su novi produkti, 3-2[(2-vinilfenil)etenil]piridin (1) i 4-2[(2-vinilfenil)etenil)piridin (2) kao smjese cis- i trans-izomera koji su sintetizirani Wittigovom reakcijom. Spojevi 1 i 2 okarakterizirani su modernim spektroskopskim metodama (jednodimenzionalni i dvodimenzionalni NMR, UV, IR spektroskopija). As a continuation of the study of the impact on the heterocyclic nucleus of the photochemical behavior of substituted o-divinylbenzene we developed a synthetic path to substituted o-divinylbenzene with pyridine nucleus. We utilized Wittig reaction to synthesize new derivatives 3-2[(2-vinylphenyl)ethenyl]pyridine (1) and 4-2[(2-vinylphenyl)ethenyl)pyridine (2) as mixtures of cis- and trans-isomers which are synthesized by Wittig reaction. Compounds 1 and 2 are characterized by modern spectroscopic methods (one- and two-dimensional NMR, UV, and IR spectroscopy).
وصف الملف: application/pdf
اللغة: Croatian
URL الوصول: https://explore.openaire.eu/search/publication?articleId=od______4000::654b5eb276f771444604f7598d04e68e
https://repozitorij.fkit.unizg.hr/islandora/object/fkit:129
حقوق: OPEN
رقم الأكسشن: edsair.od......4000..654b5eb276f771444604f7598d04e68e
قاعدة البيانات: OpenAIRE