Aging of poled ferroelectric ceramics due to relaxation of random depolarization fields by space-charge accumulation near grain boundaries

التفاصيل البيبلوغرافية
العنوان: Aging of poled ferroelectric ceramics due to relaxation of random depolarization fields by space-charge accumulation near grain boundaries
المؤلفون: Genenko, Yu. A., Glaum, J., Hirsch, O., Kungl, H., Hoffmann, M. J., Granzow, T.
المصدر: Physical Review B 80, 224109 (2009)
سنة النشر: 2009
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: Migration of charged point defects triggered by the local random depolarization field is shown to plausibly explain aging of poled ferroelectric ceramics providing reasonable time and acceptor concentration dependences of the emerging internal bias field. The theory is based on the evaluation of the energy of the local depolarization field caused by mismatch of the polarizations of neighbor grains. The kinetics of charge migration assumes presence of mobile oxygen vacancies in the material due to the intentional or unintentional acceptor doping. Satisfactory agreement of the theory with experiment on the Fe-doped lead zirconate titanate is demonstrated.
Comment: theory and experiment, 22 pages, 3 figures
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevB.80.224109
URL الوصول: http://arxiv.org/abs/0912.3382
رقم الأكسشن: edsarx.0912.3382
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevB.80.224109