Catalyst preparation for CMOS-compatible silicon nanowire synthesis

التفاصيل البيبلوغرافية
العنوان: Catalyst preparation for CMOS-compatible silicon nanowire synthesis
المؤلفون: Renard, Vincent T., Jublot, M., Gergaud, P., Cherns, P., Rouchon, D., Chabli, A., Jousseaume, V.
المصدر: Nature Nanotechnology 4 (2009) 654-657
سنة النشر: 2010
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: Metallic contamination was key to the discovery of semiconductor nanowires, but today it stands in the way of their adoption by the semiconductor industry. This is because many of the metallic catalysts required for nanowire growth are not compatible with standard CMOS (complementary metal oxide semiconductor) fabrication processes. Nanowire synthesis with those metals which are CMOS compatible, such as aluminium and copper, necessitate temperatures higher than 450 C, which is the maximum temperature allowed in CMOS processing. Here, we demonstrate that the synthesis temperature of silicon nanowires using copper based catalysts is limited by catalyst preparation. We show that the appropriate catalyst can be produced by chemical means at temperatures as low as 400 C. This is achieved by oxidizing the catalyst precursor, contradicting the accepted wisdom that oxygen prevents metal-catalyzed nanowire growth. By simultaneously solving material compatibility and temperature issues, this catalyst synthesis could represent an important step towards real-world applications of semiconductor nanowires.
Comment: Supplementary video can be downloaded on Nature Nanotechnology website
نوع الوثيقة: Working Paper
DOI: 10.1038/nnano.2009.234
URL الوصول: http://arxiv.org/abs/1001.1725
رقم الأكسشن: edsarx.1001.1725
قاعدة البيانات: arXiv