Can one measure negative specific heat in the canonical statistical ensemble?

التفاصيل البيبلوغرافية
العنوان: Can one measure negative specific heat in the canonical statistical ensemble?
المؤلفون: Staniscia, F., Turchi, A., Fanelli, D., Chavanis, P. H., De Ninno, G.
سنة النشر: 2010
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Statistical Mechanics
الوصف: According to thermodynamics, the specific heat of Boltzmannian short-range interacting systems is a positive quantity. Less intuitive properties are instead displayed by systems characterized by long-range interactions. In that case, the sign of specific heat depends on the considered statistical ensemble: negative specific heat can be found in isolated systems, which are studied in the framework of the microcanonical ensemble; on the other hand, it is generally recognized that a positive specific heat should always be measured in systems in contact with a thermal bath, for which the canonical ensemble is the appropriate one. We demonstrate that the latter assumption is not generally true: one can in principle measure negative specific heat also in the canonical ensemble if the system under scrutiny is non-Boltzmannian and/or out-of-equilibrium.
Comment: 5 pages, 3 figures
نوع الوثيقة: Working Paper
DOI: 10.1063/1.3569558
URL الوصول: http://arxiv.org/abs/1003.0631
رقم الأكسشن: edsarx.1003.0631
قاعدة البيانات: arXiv