Quantifying defects in graphene via Raman spectroscopy at different excitation energies

التفاصيل البيبلوغرافية
العنوان: Quantifying defects in graphene via Raman spectroscopy at different excitation energies
المؤلفون: Cançado, L. G., Jorio, A., Ferreira, E. H. Martins, Stavale, F., Achete, C. A., Capaz, R. B., Moutinho, M. V. O., Lombardo, A., Kulmala, T., Ferrari, A. C.
المصدر: Nano Letters 11, 3190 (2011)
سنة النشر: 2011
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science, Condensed Matter - Mesoscale and Nanoscale Physics
الوصف: We present a Raman study of Ar(+)-bombarded graphene samples with increasing ion doses. This allows us to have a controlled, increasing, amount of defects. We find that the ratio between the D and G peak intensities for a given defect density strongly depends on the laser excitation energy. We quantify this effect and present a simple equation for the determination of the point defect density in graphene via Raman spectroscopy for any visible excitation energy. We note that, for all excitations, the D to G intensity ratio reaches a maximum for an inter-defect distance ~3nm. Thus, a given ratio could correspond to two different defect densities, above or below the maximum. The analysis of the G peak width and its dispersion with excitation energy solves this ambiguity.
Comment: Fixed numerical factors in equations (5) and (6)
نوع الوثيقة: Working Paper
DOI: 10.1021/nl201432g
URL الوصول: http://arxiv.org/abs/1105.0175
رقم الأكسشن: edsarx.1105.0175
قاعدة البيانات: arXiv