Effect of Ru susbstitution on atomic displacements in the layered SmFe_{1-x}Ru_xAsO_{0.85}F_{0.15} superconductor

التفاصيل البيبلوغرافية
العنوان: Effect of Ru susbstitution on atomic displacements in the layered SmFe_{1-x}Ru_xAsO_{0.85}F_{0.15} superconductor
المؤلفون: Iadecola, A., Joseph, B., Simonelli, L., Maugeri, L., Fratini, M., Martinelli, A., Palenzona, A., Putti, M., Saini, N. L.
المصدر: Physical Review B 85, 214530 (2012)
سنة النشر: 2012
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Superconductivity, Condensed Matter - Materials Science
الوصف: The effect of Ru substitution on the local structure of layered SmFe$_{1-x}$Ru$_x$AsO$_{0.85}$F$_{0.15}$ superconductor has been studied by As $K$- and Sm $L_3$ - edges x-ray-absorption spectroscopy. The extended x-ray-absorption fine-structure measurements reveal distinct Fe-As and Ru-As bondlengths in the Ru substituted samples with the latter being $\sim$0.03 \AA\ longer. Local disorder induced by the Ru substitution is mainly confined to the FeAs layer while the SmO spacer layer sustains a relative order, consistent with the x-ray-absorption near-edge structure spectra. The results suggest that, in addition to the order/disorder in the active active iron-arsenide layer, its coupling to the rare-earth\textminus oxygen spacer layer needs to be considered for describing the electronic properties of these layered superconductors.
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevB.85.214530
URL الوصول: http://arxiv.org/abs/1206.6526
رقم الأكسشن: edsarx.1206.6526
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevB.85.214530