Spin lock composite and shaped pulses for efficient and robust pumping of dark states in magnetic resonance

التفاصيل البيبلوغرافية
العنوان: Spin lock composite and shaped pulses for efficient and robust pumping of dark states in magnetic resonance
المؤلفون: Theis, Thomas, Feng, Yesu, Wu, Tung-Lin, Warren, Warren S.
سنة النشر: 2013
المجموعة: Physics (Other)
مصطلحات موضوعية: Physics - Chemical Physics, Physics - Medical Physics
الوصف: Long-lived (symmetry protected) hyperpolarized spin states offer important new opportunities (for example, in clinical MR imaging), but existing methods for producing these states are limited by either excess energy dissipation or high sensitivity to inhomogeneities. We extend recent work on continuous-wave irradiation of nearly-equivalent spins (spin-lock induced crossing) by designing composite pulse and adiabatic shaped-pulse excitations which overcome the limitations. These composite and adiabatic pulses differ drastically from the traditional solutions in two-level systems. We also show this works in chemically equivalent spin pairs, which has the advantage of allowing for polarization transfer from and to remote spins. The approach is broadly applicable to systems where varying excitation strength induces an avoided crossing to a dark state, and thus to many other spectroscopic regimes.
Comment: 6 pages 4 figures
نوع الوثيقة: Working Paper
DOI: 10.1063/1.4851337
URL الوصول: http://arxiv.org/abs/1308.5666
رقم الأكسشن: edsarx.1308.5666
قاعدة البيانات: arXiv