Predicting the outcome of the growth of binary solids far from equilibrium

التفاصيل البيبلوغرافية
العنوان: Predicting the outcome of the growth of binary solids far from equilibrium
المؤلفون: Mannige, Ranjan V., Whitelam, Stephen
سنة النشر: 2015
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Soft Condensed Matter
الوصف: The growth of multicomponent structures in simulations and experiments often results in kinetically trapped, nonequilibrium objects. In such cases we have no general theoretical framework for predicting the outcome of the growth process. Here we use computer simulations to study the growth of two-component structures within a simple lattice model. We show that kinetic trapping happens for many choices of growth rate and inter-component interaction energies, and that qualitatively distinct kinds of kinetic trapping are found in different regions of parameter space. In a region in which the low-energy structure is an `antiferromagnet' or `checkerboard', we show that the grown nonequilibrium structure displays a component-type stoichiometry that is different to the equilibrium one but is insensitive to growth rate and solution conditions. This robust nonequilibrium stoichiometry can be predicted via a mapping to the jammed random tiling of dimers studied by Flory, a finding that suggests a way of making defined nonequilibrium structures in experiment.
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevE.93.042136
URL الوصول: http://arxiv.org/abs/1507.06267
رقم الأكسشن: edsarx.1507.06267
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevE.93.042136