تقرير
Steering proton migration in hydrocarbons using intense few-cycle laser fields
| العنوان: | Steering proton migration in hydrocarbons using intense few-cycle laser fields |
|---|---|
| المؤلفون: | Kübel, M., Siemering, R., Burger, C., Kling, Nora G., Li, H., Alnaser, A. S., Bergues, B., Zherebtsov, S., Azzeer, A. M., Ben-Itzhak, I., Moshammer, R., de Vivie-Riedle, R., Kling, M. F. |
| المصدر: | Phys. Rev. Lett. 116, 193001 (2016) |
| سنة النشر: | 2015 |
| المجموعة: | Physics (Other) |
| مصطلحات موضوعية: | Physics - Chemical Physics, Physics - Atomic and Molecular Clusters |
| الوصف: | Proton migration is a ubiquitous process in chemical reactions related to biology, combustion, and catalysis. Thus, the ability to control the movement of nuclei with tailored light, within a hydrocarbon molecule holds promise for far-reaching applications. Here, we demonstrate the steering of hydrogen migration in simple hydrocarbons, namely acetylene and allene, using waveform-controlled, few-cycle laser pulses. The rearrangement dynamics are monitored using coincident 3D momentum imaging spectroscopy, and described with a quantum-dynamical model. Our observations reveal that the underlying control mechanism is due to the manipulation of the phases in a vibrational wavepacket by the intense off-resonant laser field. Comment: 5 pages, 4 figures |
| نوع الوثيقة: | Working Paper |
| DOI: | 10.1103/PhysRevLett.116.193001 |
| URL الوصول: | http://arxiv.org/abs/1508.04018 |
| رقم الأكسشن: | edsarx.1508.04018 |
| قاعدة البيانات: | arXiv |
| DOI: | 10.1103/PhysRevLett.116.193001 |
|---|