Mesostructure anisotropy of bacterial cellulose-polyacrylamide hydrogels as studied by spin-echo small-angle neutron scattering

التفاصيل البيبلوغرافية
العنوان: Mesostructure anisotropy of bacterial cellulose-polyacrylamide hydrogels as studied by spin-echo small-angle neutron scattering
المؤلفون: Velichko, E. V., Buyanov, A. L., Chetverikov, Yu. O., Duif, C. P., Bouwman, W. G., Smyslov, R. Yu.
سنة النشر: 2016
المجموعة: Physics (Other)
مصطلحات موضوعية: Physics - Chemical Physics, Physics - Biological Physics
الوصف: The submicron- and micron-scale structures of composite hydrogels based on bacterial cellulose (BC) and polyacrylamide were studied by spin-echo small-angle neutron scattering (SESANS). These hydrogels were synthesized via free-radical polymerization of acrylamide carried out in pellicle of BC swollen in the reaction solution. No neutron scattering was observed for the samples swollen in heavy water to the equilibrium state, but a SESANS signal appeared when TbCl$_{3}$ salt was added to the solvent. The SESANS dependences obtained for these samples revealed the anisotropy of mesostructure for the hydrogels under investigation. Density inhomogeneities on the characteristic scale of 11.5 $\pm$ 0.5 $\mu$m were detected in one specific orientation of the sample, i.e. with growth plane of BC parallel to plane formed by neutron beam and spin-echo length. The uniaxial anisotropy revealed agrees with the proposed model, which attributes this behavior to the existence of the tunnel-like oriented structures inside BC.
نوع الوثيقة: Working Paper
URL الوصول: http://arxiv.org/abs/1608.00544
رقم الأكسشن: edsarx.1608.00544
قاعدة البيانات: arXiv