Resonances at very low temperature for the reaction D$_2$+H

التفاصيل البيبلوغرافية
العنوان: Resonances at very low temperature for the reaction D$_2$+H
المؤلفون: Simbotin, I., Côté, R.
سنة النشر: 2016
المجموعة: Physics (Other)
مصطلحات موضوعية: Physics - Atomic Physics, Physics - Chemical Physics
الوصف: We present numerical results for rate coefficients of reaction and vibrational quenching in the collision of H with D$_2(v,j)$ at cold and ultracold temperatures. We explore both ortho-D$_2(j\!=\!0)$ and para-D$_2(j\!=\!1)$ for several initial vibrational states $(v\leq 5)$, and find resonant structures in the energy range 0.01--10 kelvin, which are sensitive to the initial rovibrational state $(v,j)$. We compare the reaction rates for D$_2$+H with our previously obtained results for the isotopologue reaction H$_2$+D, and discuss the implications of our detailed study of this benchmark system for ultracold chemistry.
Comment: 12 pages, 7 figures
نوع الوثيقة: Working Paper
DOI: 10.1088/1361-6455/aa6821
URL الوصول: http://arxiv.org/abs/1612.08437
رقم الأكسشن: edsarx.1612.08437
قاعدة البيانات: arXiv
الوصف
DOI:10.1088/1361-6455/aa6821