Phase diagram of multiferroic KCu$_3$As$_2$O$_7$(OD)$_3$

التفاصيل البيبلوغرافية
العنوان: Phase diagram of multiferroic KCu$_3$As$_2$O$_7$(OD)$_3$
المؤلفون: Nilsen, Gøran J., Simonet, Virginie, Colin, Claire V., Okuma, Ryutaro, Okamoto, Yoshihiko, Tokunaga, Masashi, Hansen, Thomas C., Khalyavin, Dmitry D., Hiroi, Zenji
المصدر: Phys. Rev. B 95, 214415 (2017)
سنة النشر: 2017
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Strongly Correlated Electrons
الوصف: The layered compound KCu$_3$As$_2$O$_7$(OD)$_3$, comprising distorted kagome planes of $S=1/2$ Cu$^{2+}$ ions, is a recent addition to the family of type-II multiferroics. Previous zero field neutron diffraction work has found two helically ordered regimes in \kns, each showing a distinct coupling between the magnetic and ferroelectric order parameters. Here, we extend this work to magnetic fields up to $20$~T using neutron powder diffraction, capacitance, polarization, and high-field magnetization measurements, hence determining the $H-T$ phase diagram. We find metamagnetic transitions in both low temperatures phases around $\mu_0 H_c \sim 3.7$~T, which neutron powder diffraction reveals to correspond to a rotation of the helix plane away from the easy plane, as well as a small change in the propagation vector. Furthermore, we show that the sign of the ferroelectric polarization is reversible in a magnetic field, although no change is observed (or expected on the basis of the magnetic structure) due to the transition at $3.7$~T. We finally justify the temperature dependence of the polarization in both zero-field ordered phases by a symmetry analysis of the free energy expansion.
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevB.95.214415
URL الوصول: http://arxiv.org/abs/1702.03268
رقم الأكسشن: edsarx.1702.03268
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevB.95.214415