We present turbulent Schmidt number Sc_t estimations above three-dimensional urban canopies, where Sc_t is a property of the flow defined as the ratio of the eddy diffusivity of momentum (K_M) to the eddy diffusivity of mass (D_t). Despite the fact that Sc_t modelling is of great interest, inter alia, for pollutant dispersion simulations conducted via computational fluid dynamics, no universal value is known. Simultaneous measurements of fluid velocity and mass concentration are carried out in a water channel for three staggered arrays of cubical obstacles corresponding to isolated flow, wake-interference, and skimming-flow regimes. A passive tracer is released from a continuous point source located at a height z=1.67H, where H is the obstacle height. The results show an increase of Sc_t with height above the canopy for all three arrays, with values at z=2H (Sc_t = 0.6) about double compared to that at z=H. The observed Sc_t agrees well with that modelled by using a simple formulation for Sc_t based on expressions for K_M and D_t published in previous studies. Comparisons with other Sc_t models found in the literature are also presented and discussed.